Salah could become only the fourth player to reach 90 European appearances for Liverpool, after Jamie Carragher (150), Steven Gerrard (130) and Sami Hyypia (94).
Ibrahima Konate could play his 150th game for the Reds.
Dominik Szoboszlai and Virgil van Dijk have played every minute of Liverpool’s Champions League campaign this season.
Cody Gakpo made 159 appearances for PSV in all competitions and scored 55 times before he joined Liverpool in January 2023.
None of the Reds’ last 30 group-stage/league-phase matches in UEFA competition have finished in a draw, since the 1-1 result at Midtjylland in December 2020.
Liverpool have won each of their last 13 Champions League group-stage/league-phase fixtures played at Anfield.
Arne Slot will take charge of a team against PSV for the 11th time in his career, the most he has faced a single club.
So far in this season’s Champions League, PSV lost 3-1 at home to Union SG, drew 1-1 at Bayer Leverkusen, defeated Napoli 6-2 in Eindhoven and drew 1-1 at Olympiacos.
